The 3d–5d orbital repulsion of transition metals in oxyhydroxide catalysts facilitates water oxidation-Reference-Cited by-同舟云学术

The 3d–5d orbital repulsion of transition metals in oxyhydroxide catalysts facilitates water oxidation

Published:2019 Issue:24 Volume:7 Page:14455-14461
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Wang Lie¹²³⁴⁵,Wen Yunzhou¹²³⁴⁵,Ji Yujin⁶⁷⁸⁹¹⁰^ORCID,Cao Hanjie¹¹¹²⁵¹⁰,Li Shangyu¹²³⁴⁵,He Sisi¹²³⁴⁵,Bai Haipeng¹²³⁴⁵,Liu Gejun¹²³⁴⁵,Zhang Longsheng¹²³⁴⁵,Bao Hongliang¹¹¹²⁵¹⁰,Wang Jianqiang¹¹¹²⁵¹⁰¹³^ORCID,Li Youyong⁶⁷⁸⁹¹⁰^ORCID,Zhang Bo¹²³⁴⁵,Peng Huisheng¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Molecular Engineering of Polymers

2. Department of Macromolecular Science

3. Laboratory of Advanced Materials

4. Fudan University

5. Shanghai

6. Institute of Functional Nano & Soft Materials (FUNSOM)

7. Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices

8. Soochow University

9. Suzhou

10. China

11. Shanghai Institute of Applied Physics

12. Chinese Academy of Sciences

13. Dalian National Laboratory for Clean Energy

Abstract

We have developed a powerful strategy to achieve a high-efficiency NiFeIr electrocatalyst for water oxidation by using 3d–5d orbital repulsion to tune the electronic structures, combining the DFT calculations and experimental verifications.

Funder

Science and Technology Commission of Shanghai Municipality

Ministry of Science and Technology of the People's Republic of China

National Natural Science Foundation of China

Shanghai Municipal Education Commission

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/TA/C9TA03542G