Mesoporous silicas tethered with anions as quasi-solid electrolytes for lithium–metal batteries

Author:

Chen Zerui1,Xu Yifei1,Zhao Wei1,Liu Qianqian12,Liu Qian1,Hu Zhikun1,Liu Yan1,Wu Hao Bin1ORCID

Affiliation:

1. Institute for Composites Science Innovation (InCSI) and State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, China

2. Key Laboratory of Electronic Materials and Devices of Tianjin, School of Electronics and Information Engineering, Hebei University of Technology, Tianjin, China

Abstract

Mesoporous silicas tethered with anions were developed as quasi-solid electrolytes. The high grafted density of –NTf groups and their uniformly distributed negative charge endow MCM41-NLiTf with single Li-ion conductivity up to 2.4 × 10−4 S cm−1.

Funder

Natural Science Foundation of Zhejiang Province

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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