Supramolecular interactions between catalytic species allow rational control over reaction kinetics-Reference-Cited by-同舟云学术

Supramolecular interactions between catalytic species allow rational control over reaction kinetics

Published:2019 Issue:39 Volume:10 Page:9115-9124
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Teunissen Abraham J. P.¹²³⁴⁵^ORCID,Paffen Tim F. E.¹²³⁴⁵,Filot Ivo A. W.¹²³⁴⁶,Lanting Menno D.¹²³⁴⁵,van der Haas Roy J. C.¹²³⁴⁵,de Greef Tom F. A.¹²³⁴⁷^ORCID,Meijer E. W.¹²³⁴⁵^ORCID

Affiliation:

1. Institute for Complex Molecular Systems

2. Eindhoven University of Technology

3. 5600 MB Eindhoven

4. The Netherlands

5. Laboratory of Macromolecular and Organic Chemistry

6. Schuit Institute for Catalysis

7. Computational Biology

Abstract

The non-covalent interactions between two phase-transfer catalysts allow tuning of reaction kinetics from bimolecular, to pseudo 0^th order, to sigmoidal. Kinetic models and DFT calculations are used to obtain detailed insight in the system.

Funder

Nederlandse Organisatie voor Wetenschappelijk Onderzoek

Ministerie van Onderwijs, Cultuur en Wetenschap

European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC02357G

Reference48 articles.

1. Active site-directed protein regulation