Selective deuteration of pyridine using barium oxide and D<sub>2</sub> gas-Reference-Cited by-同舟云学术

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Selective deuteration of pyridine using barium oxide and D₂ gas

Published:2024 Issue:33 Volume:48 Page:14512-14515
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Wang Yun¹,Cai Yongli²³,Hao Jingai¹,Li Zhiwei¹,Cheng Tianyu¹,Yang Xinping¹,An Qingda¹,Guo Jianping²³^ORCID

Affiliation:

1. Faculty of Light Industry and Chemical Engineering, Dalian Polytechnic University, Dalian 116034, China

2. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China

3. Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

We report a transition metal-free barium oxide catalyst for selective deuteration of pyridine using D2 as a D source. The heterolytic dissociation of D2 on BaO plays a key role in the D/H exchange reaction of pyridine.

Funder

National Natural Science Foundation of China

Youth Innovation Promotion Association of the Chinese Academy of Sciences

Department of Education of Liaoning Province

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/NJ/D4NJ02512A

Reference32 articles.

1. Deuterium- and Tritium-Labelled Compounds: Applications in the Life Sciences

2. Applications of Deuterium in Medicinal Chemistry

3. Recent Developments for the Deuterium and Tritium Labeling of Organic Molecules

4. Controllable deuteration of halogenated compounds by photocatalytic D2O splitting

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