Competition between reverse water gas shift reaction and methanol synthesis from CO<sub>2</sub>: influence of copper particle size-Reference-Cited by-同舟云学术

Competition between reverse water gas shift reaction and methanol synthesis from CO₂: influence of copper particle size

Published:2022 Issue:37 Volume:14 Page:13551-13560
ISSN:2040-3364
Container-title:Nanoscale
language:en
Short-container-title:Nanoscale

Author:

Barberis Laura¹^ORCID,Hakimioun Amir H.²,Plessow Philipp N.²^ORCID,Visser Nienke L.¹,Stewart Joseph A.³^ORCID,Vandegehuchte Bart D.³,Studt Felix²⁴^ORCID,de Jongh Petra E.¹^ORCID

Affiliation:

1. Materials Chemistry and Catalysis, Debye Institute for Nanomaterials Science, Utrecht University, Universiteitsweg 99, 3584 CG Utrecht, The Netherlands

2. Institute of Catalysis Research and Technology, Karlsruhe Institute of Technology, Eggenstein-Leopoldshafen 76344, Germany

3. TotalEnergies OneTech Belgium, B-7181 Seneffe, Belgium

4. Institute for Chemical Technology and Polymer Chemistry, Karlsruhe Institute of Technology, Karlsruhe 76131, Germany

Abstract

The hydrogenation of CO2 is a structure sensitive reaction over copper nanoparticles. The particle size effect has been related to the differences in reaction intermediate coverage for different Cu facets whose abundancy vary with the particle size.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NR/D2NR02612K

Reference82 articles.

1. IPCC , 2014: Climate Change 2014: Synthesis Report. Contribution of Working Groups I, II and III to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change , Geneva, Switzerland , 2014

2. G. A.Olah , A.Goeppert and G. K. S.Prakash , Beyond Oil and Gas: The Methanol Economy , 2009

3. International Renewable Energy Agency (IRENA) , Innovation Outlook: Renewable Methanol , 2021

4. Methanol Synthesis

5. J. B.Hansen and P. E. H.Nielsen , in Handbook of Heterogeneous Catalysis , ed. G. Ertl , H. Knözinger , F. Schüth and J. Weitkamp , Wiley-VCH , Weinheim , 2008

Cited by 24 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Morphology effects of CeO2 on the performance of CaO-Cu/ CeO2 for integrated CO2 capture and conversion to CO;Separation and Purification Technology;2025-02

2. Active sites discrimination of Pt-catalyzed hydrogenation of 2-methylfuran;Catalysis Today;2025-01

3. Unraveling the mechanistic interplay between CO and CO2 hydrogenation over Ni, Co, and NiCo catalysts;Journal of Catalysis;2024-10

4. On the Structure Sensitivity of CO₂ Hydrogenation over Cu/ZrO₂: Insights into the Role of the Support and the Active Sites;ACS Catalysis;2024-09-10

5. Catalytic systems for hydrogenation of CO2 to methanol;Molecular Catalysis;2024-09