Competition between reverse water gas shift reaction and methanol synthesis from CO<sub>2</sub>: influence of copper particle size-Reference-Cited by-同舟云学术

Competition between reverse water gas shift reaction and methanol synthesis from CO₂: influence of copper particle size

Published:2022 Issue:37 Volume:14 Page:13551-13560
ISSN:2040-3364
Container-title:Nanoscale
language:en
Short-container-title:Nanoscale

Author:

Barberis Laura¹^ORCID,Hakimioun Amir H.²,Plessow Philipp N.²^ORCID,Visser Nienke L.¹,Stewart Joseph A.³^ORCID,Vandegehuchte Bart D.³,Studt Felix²⁴^ORCID,de Jongh Petra E.¹^ORCID

Affiliation:

1. Materials Chemistry and Catalysis, Debye Institute for Nanomaterials Science, Utrecht University, Universiteitsweg 99, 3584 CG Utrecht, The Netherlands

2. Institute of Catalysis Research and Technology, Karlsruhe Institute of Technology, Eggenstein-Leopoldshafen 76344, Germany

3. TotalEnergies OneTech Belgium, B-7181 Seneffe, Belgium

4. Institute for Chemical Technology and Polymer Chemistry, Karlsruhe Institute of Technology, Karlsruhe 76131, Germany

Abstract

The hydrogenation of CO2 is a structure sensitive reaction over copper nanoparticles. The particle size effect has been related to the differences in reaction intermediate coverage for different Cu facets whose abundancy vary with the particle size.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NR/D2NR02612K

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