Steric effects on the intramolecular charge transfer fluorescence of benzo[b]thiophene-1,1-dioxide bridged macrocages-Reference-Cited by-同舟云学术

Steric effects on the intramolecular charge transfer fluorescence of benzo[b]thiophene-1,1-dioxide bridged macrocages

Published:2021 Issue:28 Volume:19 Page:6328-6333
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Nobuhara Keita¹²³⁴⁵,Inagaki Yusuke¹²³⁴⁵,Setaka Wataru¹²³⁴⁵^ORCID

Affiliation:

1. Division of Applied Chemistry

2. Faculty of Urban Environmental Sciences

3. Tokyo Metropolitan University

4. Tokyo 192-0397

5. Japan

Abstract

Steric effects on ICT fluorescence were investigated. The Onsager radii for these BTO2s were increased in the following order: TMSBTO2, non-cage isomers, and caged BTO2s.

Funder

Izumi Science and Technology Foundation

Murata Science Foundation

Japan Society for the Promotion of Science

Iketani Science and Technology Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/OB/D1OB01050F

Reference34 articles.

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2. Recent advances in twisted intramolecular charge transfer (TICT) fluorescence and related phenomena in materials chemistry

3. Chemistry of organosilicon compounds. 300. .sigma..pi.* Orthogonal intramolecular charge-transfer (OICT) excited states and photoreaction mechanism of trifluoromethyl-substituted phenyldisilanes

4. First Observation of Intramolecular Charge-Transfer Emission from Jet-Cooled (p-Cyanophenyl)pentamethyldisilane in an Isolated Molecular Condition

5. Fluorescence from the intramolecular charge-transfer state of aromatic silanes

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