Addition of aluminium, zinc and magnesium hydrides to rhodium(iii)-Reference-Cited by-同舟云学术

Addition of aluminium, zinc and magnesium hydrides to rhodium(iii)

Published:2015 Issue:10 Volume:6 Page:5617-5622
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Ekkert Olga¹²³⁴⁵,White Andrew J. P.¹²³⁴⁵,Toms Harold⁶⁷⁸⁵,Crimmin Mark R.¹²³⁴⁵

Affiliation:

1. Department

2. of Chemistry

3. Imperial College London

4. London

5. UK

6. The School of Biological and Chemical Sciences

7. Queen Mary, University of London

8. London E1 4NS

Abstract

We report the addition of M–H bonds (M = Al, Zn, Mg) to a Rh(iii) intermediate generated from the reductive elimination of triethylsilane from [Cp*Rh(H)₂(SiEt₃)₂].

Funder

Engineering and Physical Sciences Research Council

Royal Society

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC01309G

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