Effects of diminished steric protection at phosphorus on stability and reactivity of oxaphosphirane complexes
Author:
Affiliation:
1. Institut für anorganische Chemie der Universität Bonn
2. 53121 Bonn
3. Germany
4. Departamento de Química Orgánica
5. Universidad de Murcia
6. 30100 Murcia
7. Spain
Abstract
Facile synthesis of oxaphosphirane complexes II, 1,3,2-dioxaphosphol-4-ene III and 1,3,2-dioxaphospholane complexes IV from Li/Cl phosphinidenoid complexes I is described.
Funder
Deutsche Forschungsgemeinschaft
European Cooperation in Science and Technology
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT01979G
Reference39 articles.
1. Zwischenstufen der α-Eliminierung
2. Chemie stabiler Lithium-α-halogenorganyle und Mechanismus carbenoider Reaktionen
3. The Electrophilic Nature of Carbenoids, Nitrenoids, and Oxenoids
4. Chemischer Nachweis eines transienten Phosphinidenoid- Komplexes
5. Facile Synthesis of Pentacarbonyltungsten(0) Complexes with Oxaphosphirane Ligands
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1. Challenging an old paradigm by demonstrating transition metal-like chemistry at a neutral nonmetal center;Nature Communications;2023-10-13
2. The quest for unligated oxaphosphiranes with phosphorus in different coordination numbers;Chemical Communications;2023
3. Regioselective N- versus P-Deprotonation of Aminophosphane Tungsten(0) Complexes;Organics;2022-06-22
4. Dimerization and Cycloaddition Reactions of Transient Tri-tert-butylphosphacyclobutadiene Generated by Lewis Acid Induced Isomerization of Tri-tert-butylphosphatetrahedrane;Journal of the American Chemical Society;2021-08-12
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