Synthesis of radiolabelled aryl azides from diazonium salts: experimental and computational results permit the identification of the preferred mechanism-Reference-Cited by-同舟云学术

Synthesis of radiolabelled aryl azides from diazonium salts: experimental and computational results permit the identification of the preferred mechanism

Published:2015 Issue:43 Volume:51 Page:8954-8957
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Joshi Sameer M.¹²³⁴⁵,de Cózar Abel⁶⁷⁸⁵⁹,Gómez-Vallejo Vanessa¹⁰²³⁴⁵,Koziorowski Jacek¹¹¹²¹³¹⁴,Llop Jordi¹²³⁴⁵,Cossío Fernando P.⁶⁷⁸⁵⁹

Affiliation:

1. Radiochemistry and Nuclear Imaging

2. CIC biomaGUNE

3. Paseo Miramón 182

4. Parque Tecnológico de San Sebastián

5. San Sebastián/Donostia

6. Departamento de Química Orgánica I

7. Facultad de Química

8. Universidad del País Vasco/Euskal Herriko Unibertsitatea (UPV/EHU)

9. Spain

10. Radiochemistry Platform

11. Department of Radiation Physics and Department of Medical and Health Sciences

12. Linköping University

13. Linköping

14. Sweden

Abstract

Experimental and computational studies support a stepwise mechanism via acyclic zwitterionic intermediates in the formation of aryl azides from diazonium salts.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C5CC01913C

Reference44 articles.

1. Notiz über Hyperbromide der Diazosäuren.

2. The Azide Method in Peptide Synthesis: Its Scope and Limitations1

3. Recent development of peptide coupling reagents in organic synthesis

4. Synthesis and biological activity of several amino analogs of thymidine

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