Nitric oxide oxidation of a Ta encapsulating Si cage nanocluster superatom (Ta@Si16) deposited on an organic substrate; a Si cage collapse indicator-Reference-Cited by-同舟云学术

Nitric oxide oxidation of a Ta encapsulating Si cage nanocluster superatom (Ta@Si16) deposited on an organic substrate; a Si cage collapse indicator

Published:2018 Issue:41 Volume:20 Page:26273-26279
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Shibuta Masahiro¹²³⁴⁵^ORCID,Niikura Toshiki⁶⁷²⁸⁵,Kamoshida Toshiaki⁶⁷²⁸⁵,Tsunoyama Hironori⁶⁷²⁸⁵^ORCID,Nakajima Atsushi¹²³⁴⁵^ORCID

Affiliation:

1. Keio Institute of Pure and Applied Sciences (KiPAS)

2. Keio University

3. 3-14-1, Hiyoshi

4. Kohoku-ku

5. Japan

6. Department of Chemistry

7. Faculty of Science and Technology

8. 3-14-1 Hiyoshi, Kohoku-ku

Abstract

Stepwise oxidative reaction of a Ta-encapsulating Si₁₆ caged nanocluster superatom upon exposure to nitric oxide is investigated by monitoring N 1s core level signals.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CP/C8CP05580G

Reference65 articles.

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3. Superatoms: Electronic and Geometric Effects on Reactivity

4. Super Atomic Clusters: Design Rules and Potential for Building Blocks of Materials

5. Thermal metal cluster anion reactions: Behavior of aluminum clusters with oxygen

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