QM/MM study on the enantioselectivity of spiroacetalization catalysed by an imidodiphosphoric acid catalyst: how confinement works
Author:
Affiliation:
1. Facultad de Ciencias Químicas
2. Universidad de Salamanca
3. Salamanca E37004
4. Spain
5. Chemistry Research Laboratory
6. Oxford OX1 3TA
7. UK
Abstract
An explanation of why confined imidodiphosphoric acid catalyst succeeds where other chiral phosphoric acid catalysts fail.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/OB/C6OB00045B
Reference63 articles.
1. Binaphthol-derived phosphoric acid as a versatile catalyst for enantioselective carbon–carbon bond forming reactions
2. Unifying Metal and Brønsted Acid Catalysis-Concepts, Mechanisms, and Classifications
3. Brønsted-Acid-Catalyzed Asymmetric Multicomponent Reactions for the Facile Synthesis of Highly Enantioenriched Structurally Diverse Nitrogenous Heterocycles
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