Understanding the different reactivity of (Z)- and (E)-β-nitrostyrenes in [3+2] cycloaddition reactions. An MEDT study
Author:
Affiliation:
1. Department of Organic Chemistry
2. University of Valencia
3. Spain
4. Faculty of Chemical Engineering and Technology
5. Department of Organic Chemistry and Technology
6. Cracow University of Technology
7. 31-155 Cracow
8. Poland
Abstract
The different reactivity and selectivities of isomeric E/Z β-nitrostyrenes in polar zw-type [3+2] cycloaddition reactions is explained within MEDT.
Funder
Infrastruktura PL-Grid
H2020 Marie Skłodowska-Curie Actions
Ministerio de Ciencia, Innovación y Universidades
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/RA/D1RA00891A
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4. A DFT study on the molecular mechanism of the conjugated nitroalkenes polymerization process initiated by selected unsaturated nucleophiles
5. [3+2] Cycloaddition of diaryldiazomethanes with (E)-3,3,3-trichloro-1-nitroprop-1-ene: An experimental, theoretical and structural study
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