Carbopalladation of bromoene-alkynylsilanes: mechanistic insights and synthesis of fused-ring bicyclic silanes and phenols-Reference-Cited by-同舟云学术

Carbopalladation of bromoene-alkynylsilanes: mechanistic insights and synthesis of fused-ring bicyclic silanes and phenols

Published:2014 Issue:6 Volume:1 Page:661-673
ISSN:2052-4129
Container-title:Org. Chem. Front.
language:en
Short-container-title:Org. Chem. Front.

Author:

Cordonnier Marie-Caroline A.¹²³,Kan S. B. Jennifer⁴⁵⁶,Gockel Birgit¹²³,Goh Shermin S.¹²³,Anderson Edward A.¹²³

Affiliation:

1. Chemistry Research Laboratory

2. University of Oxford

3. Oxford, UK

4. Department of Chemistry

5. University of Cambridge

6. Cambridge, UK

Abstract

Palladium-catalyzed cyclizations of silylated bromoenynes lead to bicyclic cyclohexadienes that are precursors to enones and phenols. Novel cyclization pathways and mechanistic insights are also disclosed.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/QO/C4QO00123K

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