Non-stabilized diazoalkane synthesis via the oxidation of free hydrazones by iodosylbenzene and application in in situ MIRC cyclopropanation-Reference-Cited by-同舟云学术

Non-stabilized diazoalkane synthesis via the oxidation of free hydrazones by iodosylbenzene and application in in situ MIRC cyclopropanation

Published:2019 Issue:13 Volume:10 Page:3802-3806
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Allouche Emmanuelle M. D.¹²³⁴,Charette André B.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Université de Montréal

3. Montreal

4. H3C 3J7 Canada

Abstract

Highly reactive non-stabilized diazo compounds are generated from free hydrazones using iodosylbenzene. In situ MIRC cyclopropanations were performed on a wide array of substrates.

Funder

Canada Research Chairs

Canada Foundation for Innovation

Natural Sciences and Engineering Research Council of Canada

Fonds de Recherche du Québec – Nature et Technologies

Université de Montréal

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C8SC05558K

Reference60 articles.

1. M. Regitz and G.Maas , Diazo Compounds , Academic Press , 1986 , pp. 3–64

2. M. P. Doyle , M. A.McKervey and Y.Tao , in Modern Catalytic Methods for Organic Synthesis with Diazo Compounds: From Cyclopropanes to Ylides , Wiley-VCH , Weinheim , 1998 , pp. 1–65

3. Modern Organic Synthesis with α-Diazocarbonyl Compounds

4. Diazo Compounds: Versatile Tools for Chemical Biology

5. DIAZOMETHANE

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