Substitution lability of the perfluorinated Cp* ligand in Rh(<scp>i</scp>) complexes-Reference-Cited by-同舟云学术

Substitution lability of the perfluorinated Cp* ligand in Rh(i) complexes

Published:2023 Issue:17 Volume:52 Page:5496-5502
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Parche Joshua¹,Rupf Susanne M.¹^ORCID,Sievers Robin¹,Malischewski Moritz¹^ORCID

Affiliation:

1. Freie Universität Berlin, Institute of Inorganic Chemistry, Fabeckstr. 34-36, 14195 Berlin, Germany

Abstract

Fluorinated pyridines can displace the anionic [C5(CF3)5]− ligand in [Rh(COD)(C5(CF3)5)], however the reaction is reversible in weakly coordinating solvents as CHCl3.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT00425B

Reference33 articles.

1. Relative binding affinities of fluorobenzene ligands in cationic rhodium bisphosphine η6–fluorobenzene complexes probed using collision-induced dissociation

2. Coordination and Oxidative Addition at a Low-Coordinate Rhodium(I)β-Diiminate Centre

3. Transformations of Chloroarenes, Catalyzed by Transition-Metal Complexes

4. Transition metal complexes of the pentacyanocyclopentadienide anion

5. Intermolecular Hydroacylation: High Activity Rhodium Catalysts Containing Small-Bite-Angle Diphosphine Ligands

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