New phenyl–nickel complexes of bulky 2-iminopyrrolyl chelates: synthesis, characterisation and application as aluminium-free catalysts for the production of hyperbranched polyethylene-Reference-Cited by-同舟云学术

New phenyl–nickel complexes of bulky 2-iminopyrrolyl chelates: synthesis, characterisation and application as aluminium-free catalysts for the production of hyperbranched polyethylene

Published:2018 Issue:44 Volume:47 Page:15857-15872
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Figueira Cláudia A.¹²³⁴⁵^ORCID,Lopes Patrícia S.¹²³⁴⁵^ORCID,Gomes Clara S. B.¹²³⁴⁵^ORCID,Gomes Joselaine C. S.¹²³⁴⁵^ORCID,Lemos Francisco⁶²³⁴⁵^ORCID,Gomes Pedro T.¹²³⁴⁵^ORCID

Affiliation:

1. Centro de Química Estrutural

2. Departamento de Engenharia Química

3. Instituto Superior Técnico

4. Universidade de Lisboa

5. 1049-001 Lisboa

6. CERENA

Abstract

New mono(5-aryl-2-(N-arylformimino)pyrrolyl) Ni(ii) complexes were synthesised and tested as aluminium-free catalysts for the polymerisation of ethylene, yielding hyperbranched oligo-/polyethylenes.

Funder

Fundação para a Ciência e a Tecnologia

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT02824A

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