Inside or outside the box? Effect of substrate location on coordination-cage based catalysis-Reference-Cited by-同舟云学术

Inside or outside the box? Effect of substrate location on coordination-cage based catalysis

Published:2022 Issue:30 Volume:51 Page:11277-11285
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Solea Atena B.¹^ORCID,Sudittapong Burin¹^ORCID,Taylor Christopher G. P.¹^ORCID,Ward Michael D.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Warwick, Coventry CV4 7AL, UK

Abstract

The cavity is not everything! Catalysed hydrolysis of 4-nitrophenylacetate is inhibited inside a cage (left), but hydrolysis of diacetylfluorescein (right) is catalysed by the exterior surface.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT01713J

Reference51 articles.

1. Catalytic reactions within the cavity of coordination cages

2. Supramolecular Catalysis in Metal–Ligand Cluster Hosts

3. Functional Molecular Flasks: New Properties and Reactions within Discrete, Self-Assembled Hosts

4. Size-Selective Molecular Flasks

5. Self-Assembled Tetrahedral Hosts as Supramolecular Catalysts

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