Comparison of π-hole tetrel bonding with σ-hole halogen bonds in complexes of XCN (X = F, Cl, Br, I) and NH3-Reference-Cited by-同舟云学术

Comparison of π-hole tetrel bonding with σ-hole halogen bonds in complexes of XCN (X = F, Cl, Br, I) and NH3

Published:2016 Issue:5 Volume:18 Page:3581-3590
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Nziko Vincent de Paul N.¹²³⁴,Scheiner Steve¹²³⁴

Affiliation:

1. Department of Chemistry and Biochemistry

2. Utah State University

3. Logan

4. USA

Abstract

In addition to the standard halogen bond formed when NH₃approaches XCN (X = F, Cl, Br, I) along its molecular axis, a perpendicular approach is also possible, toward a π-hole that is present above the X–C bond.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C5CP07545A

Reference95 articles.

1. Halogen bonds in biological molecules

2. Theoretical studies of van der Waals molecules and intermolecular forces

3. Anion Receptors Composed of Hydrogen- and Halogen-Bond Donor Groups: Modulating Selectivity With Combinations of Distinct Noncovalent Interactions

4. CH/π hydrogen bonds in organic and organometallic chemistry

5. A cryospectroscopic study of the blue-shifting C–H⋯O bonded complexes of pentafluoroethane with dimethyl ether-d6, acetone-d6 and oxirane-d4

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