Upper limit to the ultimate achievable emission wavelength in near-IR emitting cyclometalated iridium complexes

Author:

Penconi Marta123ORCID,Cazzaniga Marco123,Kesarkar Sagar123ORCID,Mussini Patrizia R.45673ORCID,Ceresoli Davide123ORCID,Bossi Alberto123ORCID

Affiliation:

1. Istituto di Scienze e Tecnologie Molecolari del CNR (ISTM – CNR) via Golgi19, 20133 Milan

2. 20138 Milan and SmartMatLab Centre, via Golgi19, 20133 Milan

3. Italy

4. Dipartimento di Chimica

5. Università degli Studi di Milano

6. and SmartMatLab Centre

7. 20133 Milano

Abstract

A spectroscopic, electrochemical and computational study envisaging the use of Pt(ii) cyclometalated complexes to predict the lower emission energy limit in Ir(iii) complexes with the same cyclometalated C^N ligands.

Funder

Fondazione Cariplo

Publisher

Springer Science and Business Media LLC

Subject

Physical and Theoretical Chemistry

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4. The triplet state of organo-transition metal compounds. Triplet harvesting and singlet harvesting for efficient OLEDs

5. M. E. Thompson , P. E.Djurovich, S.Barlow and S.Marder, Organometallic Complexes for Optoelectronic Applications, in Comprehensive Organometallic Chemistry, ed. D. O'Hare, Elsevier, Oxford, 2007, vol. 12, pp. 101–194

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