Zinc amidinate-catalysed cyclization reaction of carbodiimides and alkynes. An insight into the mechanism-Reference-Cited by-同舟云学术

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Zinc amidinate-catalysed cyclization reaction of carbodiimides and alkynes. An insight into the mechanism

Published:2024 Issue:24 Volume:53 Page:10050-10054
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Parra-Cadenas Blanca¹,Ginés Carlos¹,García-Vivó Daniel²^ORCID,Elorriaga David²^ORCID,Carrillo-Hermosilla Fernando¹^ORCID

Affiliation:

1. Departamento de Química Inorgánica, Orgánica y Bioquímica-Centro de Innovación en Química Avanzada (ORFEO–CINQA), Facultad de Ciencias y Tecnologías Químicas, Universidad de Castilla-La Mancha, 13071 Ciudad Real, Spain

2. Departamento de Química Orgánica e Inorgánica, Instituto Universitario de Química Organometálica “Enrique Moles”, Universidad de Oviedo, Julián Clavería 8, 33006 Oviedo, Spain

Abstract

A novel method for synthesizing iminopyridines using zinc has been established. The proposed mechanism highlights the crucial role of zinc amidinato intermediates in this synthesis.

Funder

Ministerio de Ciencia e Innovación

Universidad de Castilla-La Mancha

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT01265H

Reference26 articles.

1. Origins, Current Status, and Future Challenges of Green Chemistry

2. Rise of the Zinc Age in Homogeneous Catalysis?

3. Recent Advances and Perspectives in the Synthesis of Heterocycles via Zinc Catalysis

4. Zinc-Catalyzed Organic Synthesis: CC, CN, CO Bond Formation Reactions

5. Simple, Versatile, and Efficient Catalysts for Guanylation of Amines

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