Tuning the formal potential of ferrocyanide over a 2.1 V range-Reference-Cited by-同舟云学术

Tuning the formal potential of ferrocyanide over a 2.1 V range

Published:2019 Issue:12 Volume:10 Page:3623-3626
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

McNicholas Brendon J.¹²³⁴⁵^ORCID,Grubbs Robert H.¹²³⁴⁵^ORCID,Winkler Jay R.¹²³⁴⁵^ORCID,Gray Harry B.¹²³⁴⁵,Despagnet-Ayoub Emmanuelle¹²³⁴⁵^ORCID

Affiliation:

1. Beckman Institute

2. Division of Chemistry and Chemical Engineering

3. California Institute of Technology

4. Pasadena

5. USA

Abstract

Coordination of tris(pentafluorophenyl)borane to hexacyanoferrate shifts the formal potential by over 2.1 V while maintaining electrochemical reversibility.

Funder

National Science Foundation

Division of Chemistry

Arnold and Mabel Beckman Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C8SC04972F

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5. Metal complexes as probes of donor-acceptor interaction. Vibrational spectra of (.pi.-C5H5)Fe(CO)2(CNMX3) (M = Boron, X = Hydrogen, fluorine, chlorine, bromine, or methyl; M = aluminum or gallium, X = chlorine or methyl)

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