Stabilization of intermediate Mo oxidation states by Nb doping enhancing methane aromatization on Mo/HZSM-5 catalysts

Author:

Peters Stefan1ORCID,Bartling Stephan1ORCID,Parlinska-Wojtan Magdalena2,Wotzka Alexander1,Buzanich Ana Guilherme3ORCID,Wohlrab Sebastian1ORCID,Abdel-Mageed Ali M.1ORCID

Affiliation:

1. Leibniz-Institut für Katalyse (LIKAT), 18059, Rostock, Germany

2. Institute of Nuclear Physics, Polish Academy of Sciences, 31-342 Krakow, Poland

3. Federal Institute for Materials Research and Testing (BAM), 12489 Berlin, Germany

Abstract

The dehydroaromatization of methane is a promising process to produce aromatics and ultra-pure hydrogen. Increased yields and stability of Mo/HZSM-5 against irreversible deactivation were achieved via a redox interaction by doping with otherwise inert Nb.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

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