Exploring Au(<scp>i</scp>) involving halogen bonding with N-heterocyclic carbene Au(<scp>i</scp>) aryl complexes in crystalline media-Reference-Cited by-同舟云学术

Exploring Au(i) involving halogen bonding with N-heterocyclic carbene Au(i) aryl complexes in crystalline media

Published:2023 Issue:17 Volume:14 Page:4485-4494
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Mikherdov Alexander S.¹^ORCID,Jin Mingoo¹^ORCID,Ito Hajime¹²^ORCID

Affiliation:

1. Institute for Chemical Reaction Design and Discovery (WPI-ICReDD), Hokkaido University, Sapporo, Hokkaido 060-8628, Japan

2. Division of Applied Chemistry, Graduate School of Engineering, Hokkaido University, Sapporo, Hokkaido 060-8628, Japan

Abstract

The halogen bonding involving the Au(i) metal center was systematically studied using a series of nine co-crystals between NHC Au(i) aryl complexes and iodoperfluoroarenes through XRD and solid-state NMR techniques, as well as DFT calculations.

Funder

Core Research for Evolutional Science and Technology

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC00373F

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