Photofragmentation mechanisms in protonated chiral cinchona alkaloids
Author:
Affiliation:
1. Institut des Sciences Moléculaires d'Orsay (ISMO)
2. CNRS
3. Univ. Paris-Sud
4. Université Paris-Saclay
5. France
6. Laboratoire de Chimie Physique
7. UMR8000, and CNRS
8. Orsay
Abstract
Photo-fragmentation of protonated alkaloids results in C8–C9 cleavage accompanied or not by hydrogen migration, with a stereochemistry-dependent branching ratio.
Funder
Agence Nationale de la Recherche
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP04041A
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