Understanding the role of supported Rh atoms and clusters during hydroformylation and CO hydrogenation reactions with <i>in situ</i>/<i>operando</i> XAS and DRIFT spectroscopy-Reference-Cited by-同舟云学术

Understanding the role of supported Rh atoms and clusters during hydroformylation and CO hydrogenation reactions with in situ/operando XAS and DRIFT spectroscopy

Published:2024 Issue:31 Volume:15 Page:12369-12379
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Sarma Bidyut Bikash¹²³^ORCID,Neukum Dominik²^ORCID,Doronkin Dmitry E.¹²^ORCID,Lakshmi Nilayam Ajai Raj⁴^ORCID,Baumgarten Lorena¹²^ORCID,Krause Bärbel⁵^ORCID,Grunwaldt Jan-Dierk¹²^ORCID

Affiliation:

1. Institute for Chemical Technology and Polymer Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstraße 20, 76131 Karlsruhe, Germany

2. Institute of Catalysis Research and Technology, KIT, Hermann-von Helmholtz Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

3. Laboratoire de Chimie de Coordination (LCC), CNRS, Université de Toulouse, INPT, 205 route de Narbonne, 31077 Toulouse Cedex 4, France

4. Institute of Nanotechnology, KIT, Hermann-von-Helmholtz Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

5. Institut für Photonenforschung und Synchrotronstrahlung (IPS), KIT, Hermann-von-Helmholtz Platz 1, D-76021 Karlsruhe, Germany

Abstract

Dynamic structural change of Rh single atom catalysts (SACs) is key during hydroformylation and CO hydrogenation reactions.

Funder

Deutsche Forschungsgemeinschaft

Centre National de la Recherche Scientifique

Helmholtz Association

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC02907K

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