Reversible nickel-metallacycle formation with a phosphinimine-based pincer ligand
Author:
Affiliation:
1. P. Roy and Diana T. Vagelos Laboratories
2. Department of Chemistry
3. University of Pennsylvania
4. USA
Abstract
A phosphinimine-based pincer ligand was found to reversibly form nickel-containing metallacycles.
Funder
Division of Chemistry
Charles E. Kaufman Foundation
National Institute of General Medical Sciences
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT01118E
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1. A Low‐Spin Three‐Coordinate Cobalt(I) Complex and Its Reactivity toward H 2 and Silane
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3. Oxidative Addition of N−C and N−H Bonds to Zerovalent Nickel, Palladium, and Platinum
4. Chemical Non-Innocence of an Aliphatic PNP Pincer Ligand
5. Complexes with Nitrogen-Centered Radical Ligands: Classification, Spectroscopic Features, Reactivity, and Catalytic Applications
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3. Synthesis, structural characterization, and bonding analysis of two-coordinate copper(i) and silver(i) complexes of pyrrole-based bis(phosphinimine): new metal–pyrrole ring π-interactions;Dalton Transactions;2021
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