A regioselectivity switch in Pd-catalyzed hydroallylation of alkynes
Author:
Affiliation:
1. Dalian Institute of Chemical Physics
2. Chinese Academy of Sciences
3. Dalian 116023
4. P. R. China
5. University of Chinese Academy of Sciences
6. Department of Chemistry
7. University of California
8. Irvine
9. USA
Abstract
Through rational evaluation of ligands and promoters, the reactivity of a key Pd(ii) species towards transmetalation or β-H elimination is manipulated.
Funder
Dalian Institute of Chemical Physics
National Natural Science Foundation of China
National Institutes of Health
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC01527B
Reference86 articles.
1. For a book, see: J. F.Hartwig , Organotransition Metal Chemistry: From Bonding to Catalysis , University Science Books , Sausalito , 2010
2. Palladium-Catalyzed Cross-Coupling Reactions of Organoboron Compounds
3. Palladium-Catalyzed Coupling Reactions of Aryl Chlorides
4. Advances in Transition Metal (Pd,Ni,Fe)-Catalyzed Cross-Coupling Reactions Using Alkyl-organometallics as Reaction Partners
5. Cross-Coupling Reactions Of Organoboranes: An Easy Way To Construct CC Bonds (Nobel Lecture)
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