Chain-length dependence of the propagation rate coefficient for methyl acrylate polymerization at 25 °C investigated by the PLP-SEC method-Reference-Cited by-同舟云学术

Chain-length dependence of the propagation rate coefficient for methyl acrylate polymerization at 25 °C investigated by the PLP-SEC method

Published:2022 Issue:21 Volume:13 Page:3053-3062
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Nikitin Anatoly N.¹^ORCID,Dušička Eva²^ORCID,Lacík Igor²³^ORCID,Hutchinson Robin A.⁴^ORCID

Affiliation:

1. Institute on Laser and Information Technologies of Russian Academy of Sciences – Branch of Federal Scientific Research Center “Crystallography and Photonics” of Russian Academy of Sciences, Svyatoozerskaya 1, 140700 Shatura, Moscow Region, Russia

2. Polymer Institute of the Slovak Academy of Sciences, Dúbravská cesta 9, 845 41 Bratislava, Slovakia

3. Centre for Advanced Materials Application of the Slovak Academy of Sciences, Dúbravská cesta 9, 845 11, Bratislava, Slovakia

4. Department of Chemical Engineering, Dupuis Hall, Queen's University, Kingston, Ontario K7L 3N6, Canada

Abstract

The marked chain-length dependence of the propagation rate coefficient of long-chain radicals has been determined for methyl acrylate bulk polymerization at 25 °C through the analysis of data obtained by the PLP-SEC method applying novel approaches.

Funder

Vedecká Grantová Agentúra MŠVVaŠ SR a SAV

Ministry of Science and Higher Education of the Russian Federation

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2022/PY/D2PY00225F

Reference51 articles.

1. Is the rate constant of chain propagationkp in radical polymerization really chain-length independent?

2. Free-Radical Propagation Rate Coefficients via n-Pulse Periodic Polymerization

3. Absolute rate constants for radical-monomer reactions

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