Trifluoromethylarylation of alkenes using anilines-Reference-Cited by-同舟云学术

Trifluoromethylarylation of alkenes using anilines

Published:2023 Issue:43 Volume:14 Page:12083-12090
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Corral Suarez Carlos¹²^ORCID,Colomer Ignacio¹²^ORCID

Affiliation:

1. Instituto de Química Orgánica General (IQOG), CSIC, Juan de la Cierva 3, 28006 Madrid, Spain

2. IMDEA Nanociencia, Faraday 9, 28049 Madrid, Spain

Abstract

This work unlocks the use of anilines in the selective trifluoromethylarylation of olefins via a mild protocol that avoids transition metals, expensive photocatalysts and additives, where hexafluoroisopropanol is a unique solvent that promotes it.

Funder

Ministerio de Ciencia e Innovación

Consejo Superior de Investigaciones Científicas

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC03868H

Reference75 articles.

1. Photoinduced Three-Component Reactions of Tetracyanobenzene with Alkenes in the Presence of 1,3-Dicarbonyl Compounds as Nucleophiles

2. Ni-Catalyzed Regioselective Alkylarylation of Vinylarenes via C(sp3)–C(sp3)/C(sp3)–C(sp2) Bond Formation and Mechanistic Studies

3. Rapid Synthesis of γ-Arylated Carbonyls Enabled by the Merge of Copper- and Photocatalytic Radical Relay Alkylarylation of Alkenes

4. Cu-Catalyzed Enantioselective Alkylarylation of Vinylarenes Enabled by Chiral Binaphthyl–BOX Hybrid Ligands

5. Organozinc pivalates for cobalt-catalyzed difluoroalkylarylation of alkenes

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