Comparison of homogeneous and heterogeneous catalysts in dye-sensitised photoelectrochemical cells for alcohol oxidation coupled to dihydrogen formation

Author:

Bruggeman D. F.1,Mathew S.1ORCID,Detz R. J.2ORCID,Reek J. N. H.1ORCID

Affiliation:

1. Homogeneous, Supramolecular and Bio-Inspired Catalysis, van 't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH Amsterdam, The Netherlands

2. Netherlands Organisation for Applied Scientific Research (TNO) - Energy Transition Studies, Radarweg 60, Amsterdam, The Netherlands

Abstract

Dye-sensitised photoelectrochemical cells (DSPECs) for light-driven oxidative organic reactions and simultaneous reductive hydrogen production are reported, using TEMPO as catalyst/mediator either in homogeneous phase or immobilized on the electrode.

Funder

Nederlandse Organisatie voor Wetenschappelijk Onderzoek

Publisher

Royal Society of Chemistry (RSC)

Subject

Energy Engineering and Power Technology,Fuel Technology,Renewable Energy, Sustainability and the Environment

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