Silyl formates as hydrosilane surrogates for the transfer hydrosilylation of ketones-Reference-Cited by-同舟云学术

Silyl formates as hydrosilane surrogates for the transfer hydrosilylation of ketones

Published:2022 Issue:43 Volume:58 Page:6308-6311
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Romero R. Martin¹^ORCID,Thyagarajan Neethu¹,Hellou Nora¹,Chauvier Clément¹^ORCID,Godou Timothé¹,Anthore-Dalion Lucile¹^ORCID,Cantat Thibault¹^ORCID

Affiliation:

1. Université Paris-Saclay, CEA, CNRS, NIMBE, 91191 Gif-sur-Yvette, France

Abstract

The transfer hydrosilylation of ketones with silyl formates was unlocked, relying on the crucial role of a cooperative PNHP ligand.

Funder

H2020 European Research Council

Centre National de la Recherche Scientifique

Commissariat à l'Énergie Atomique et aux Énergies Alternatives

Institut de France

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC00666A

Reference40 articles.

1. B.Marciniec , in Hydrosilylation: A Comprehensive Review on Recent Advances , ed. B. Marciniec , Springer Netherlands , Dordrecht , 2009 , pp. 3–51

2. Electrophilic Activation of Silicon-Hydrogen Bonds in Catalytic Hydrosilations

3. Transfer Hydrosilylation

4. Silylated Cyclohexadienes in Radical Chain Hydrosilylations

5. Radical Transfer Hydrosilylation/Cyclization Using Silylated Cyclohexadienes

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