Role of coherent nuclear motion in the ultrafast intersystem crossing of ruthenium complexes
Author:
Affiliation:
1. Department of Chemistry
2. Pohang University of Science and Technology (POSTECH)
3. Pohang 37673
4. Korea
5. KAIST
6. Daejeon 34141
Abstract
Ultrafast intersystem crossing (ISC) of ruthenium complexes is time-resolved directly. Coherent nuclear wave packets suggest that metal–ligand stretching or symmetry breaking vibrational modes are strongly coupled with the ISC.
Funder
National Research Foundation of Korea
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP05368F
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