Polar derivatives of [closo-1-CB9H10]− and [closo-1-CB11H12]− anions as high Δε additives to a nematic host: a comparison of the CH2CH2 and COO linking groups

Author:

Jakubowski Rafał1234ORCID,Pecyna Jacek5678ORCID,Ali Muhammad O.5678ORCID,Pietrzak Anna56789ORCID,Friedli Andrienne C.5678ORCID,Kaszyński Piotr12345ORCID

Affiliation:

1. Centre of Molecular and Macromolecular Studies

2. Polish Academy of Sciences

3. 90-363 Łódź

4. Poland

5. Department of Chemistry

6. Middle Tennessee State University

7. Murfreesboro

8. USA

9. X-ray Crystallographic Laboratory

Abstract

Liquid crystalline pyridinium zwitterions of [closo-1-CB9H10] perform better as polar potential components of LCD materials than the sulfonium or [closo-1-CB11H12] analogs on the basis of solubility and Maier–Meier analysis.

Funder

Fundacja na rzecz Nauki Polskiej

Narodowe Centrum Nauki

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference38 articles.

1. P. Kaszynski , In Handbook of Boron Science , ed. N. S. Hosmane and R. Eagling , World Scientific , London , 2018 , vol. 3 , pp. 57–114

2. S. Naemura , in Physical Properties of Liquid Crystals: Nematics , ed. D. A. Dunmur , A. Fukuda and G. R. Luckhurst , IEE , London , 2001 , pp. 523–581

3. Nematic Liquid Crystals for Active Matrix Displays: Molecular Design and Synthesis

4. Advanced liquid crystals for television

5. S. Urban , in Physical Properties of Liquid Crystals: Nematics , ed. D. A. Dunmur , A. Fukuda and G. R. Luckhurst , IEE , London , 2001 , pp. 267–276

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