Polar derivatives of [closo-1-CB9H10]− and [closo-1-CB11H12]− anions as high Δε additives to a nematic host: a comparison of the CH2CH2 and COO linking groups
Author:
Affiliation:
1. Centre of Molecular and Macromolecular Studies
2. Polish Academy of Sciences
3. 90-363 Łódź
4. Poland
5. Department of Chemistry
6. Middle Tennessee State University
7. Murfreesboro
8. USA
9. X-ray Crystallographic Laboratory
Abstract
Liquid crystalline pyridinium zwitterions of [closo-1-CB9H10]− perform better as polar potential components of LCD materials than the sulfonium or [closo-1-CB11H12]− analogs on the basis of solubility and Maier–Meier analysis.
Funder
Fundacja na rzecz Nauki Polskiej
Narodowe Centrum Nauki
National Science Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT00211B
Reference38 articles.
1. P. Kaszynski , In Handbook of Boron Science , ed. N. S. Hosmane and R. Eagling , World Scientific , London , 2018 , vol. 3 , pp. 57–114
2. S. Naemura , in Physical Properties of Liquid Crystals: Nematics , ed. D. A. Dunmur , A. Fukuda and G. R. Luckhurst , IEE , London , 2001 , pp. 523–581
3. Nematic Liquid Crystals for Active Matrix Displays: Molecular Design and Synthesis
4. Advanced liquid crystals for television
5. S. Urban , in Physical Properties of Liquid Crystals: Nematics , ed. D. A. Dunmur , A. Fukuda and G. R. Luckhurst , IEE , London , 2001 , pp. 267–276
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1. Substituent effects on the [1-closo-CB9H10]− anion geometry: experimental and DFT studies;CrystEngComm;2023
2. Synthesis and structure of 1-(p-cyanophenyl)-1-carba-closo-decaborate [1-(p-NCC6H4)-1-CB9H9]−;Russian Chemical Bulletin;2022-02
3. New approaches to the functionalization of the 1-carba-closo-decaborate anion;Chemical Communications;2022
4. Improved and Scalable Synthesis of [Et4N][closo-1-CHB9H9];Organometallics;2021-10-13
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