From ethene to propene (ETP) on tailored silica–alumina supports with isolated Ni(<scp>ii</scp>) sites: uncovering the importance of surface nickel aluminate sites and the carbon-pool mechanism-Reference-Cited by-同舟云学术

From ethene to propene (ETP) on tailored silica–alumina supports with isolated Ni(ii) sites: uncovering the importance of surface nickel aluminate sites and the carbon-pool mechanism

Published:2022 Issue:19 Volume:12 Page:5861-5868
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Chen Zixuan¹^ORCID,Docherty Scott R.²^ORCID,Florian Pierre³^ORCID,Kierzkowska Agnieszka¹^ORCID,Moroz Ilia B.²^ORCID,Abdala Paula M.¹^ORCID,Copéret Christophe²^ORCID,Müller Christoph R.¹^ORCID,Fedorov Alexey¹^ORCID

Affiliation:

1. Laboratory of Energy Science and Engineering, ETH Zürich, 8092 Zürich, Switzerland

2. Department of Chemistry and Applied Biosciences, ETH Zürich, 8093 Zürich, Switzerland

3. CNRS, CEMHTI UPR3079, University of Orléans, F-45071 Orléans, France

Abstract

The ethene-to-propene reaction on Ni catalysts correlates with the formation of alkylated aromatic species. The deactivation of surface Ni aluminate sites can be reversed by calcination, while the deactivation of Ni silicate sites is irreversible.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Eidgenössische Technische Hochschule Zürich

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CY/D2CY01272C

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