Cyclopalladated complexes containing 2-C6R4PPh2 ligands (R = H, F): one-electron electrochemical reduction leading to metal–carbon σ-bond cleavage via palladium(i)-Reference-Cited by-同舟云学术

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Cyclopalladated complexes containing 2-C6R4PPh2 ligands (R = H, F): one-electron electrochemical reduction leading to metal–carbon σ-bond cleavage via palladium(i)

Published:2015 Issue:7 Volume:44 Page:3367-3377
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kar Gopa¹²³⁴⁵,Privér Steven H.¹²³⁴⁵,Jones Lathe A.¹²³⁴⁵,Guo Si-Xuan⁶⁷⁸⁵,Torriero Angel A. J.⁶⁷⁸⁵,Bond Alan M.⁶⁷⁸⁵,Bennett Martin A.⁹¹⁰¹¹⁵,Bhargava Suresh K.¹²³⁴⁵

Affiliation:

1. Centre for Advanced Materials and Industrial Chemistry (CAMIC)

2. School of Applied Sciences (Applied Chemistry)

3. RMIT University

4. Melbourne

5. Australia

6. School of Chemistry

7. Monash University

8. Clayton

9. Research School of Chemistry

10. Australian National University

11. Canberra

Abstract

Cyclopalladated complexes containing the 2-C₆F₄PPh₂ fragment have been prepared and their electrochemical reduction behaviour investigated.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT03268C

Reference29 articles.

1. Ortho-metallated transition metal complexes derived from tertiary phosphine and arsine ligands

2. Synthesis and X-ray Crystallographic Characterization of (μ-(Diphenylphosphino)phenyl-C2,P)palladium Bromide. A Novel Tetranuclear Metalated Compound

3. Synthesis, Reactivity, and X-ray Crystallographic Characterization of Mono-, Di-, and Tetranuclear Palladium(II)-Metalated Species

4. A Triad of Bis(orthometalated) d8-Complexes Containing Four-Membered Rings

5. Bidentate Chelate Complexes of Palladium(II) with the Carbanion 2-C6F4PPh2 and Their Transformation into Complexes Containing Bridging 2-C6F4PPh2

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4. The use of [2-C 6 R 4 PPh 2 ] − (R = H, F) and related carbanions as building blocks in coordination chemistry;Coordination Chemistry Reviews;2018-09

5. SNS versus SNN Pincer Ligands: Electrochemical Studies and Their Palladium(II) Complexes as Electro-Catalyst for Proton Reduction;ChemistrySelect;2018-07-30

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