Evaluation of two aza-crown ether-based multiple diglycolamide-containing ligands for complexation with the tetravalent actinide ions Np4+ and Pu4+: extraction and DFT studies

Author:

Ansari Seraj A.123ORCID,Bhattacharyya Arunasis123,Mohapatra Prasanta K.123ORCID,Egberink Richard J. M.45678,Huskens Jurriaan45678ORCID,Verboom Willem45678ORCID

Affiliation:

1. Radiochemistry Division, Bhabha Atomic Research Centre

2. Mumbai-400085

3. India

4. Laboratory of Molecular Nanofabrication

5. MESA+ Institute for Nanotechnology

6. University of Twente

7. 7500 AE Enschede

8. The Netherlands

Abstract

Two multiple diglycolamide (DGA)-containing aza-crown ether ether-based extractants were evaluated for the extraction of the tetravalent actinide ions Np4+ and Pu4+.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference42 articles.

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2. THE TRUEX PROCESS - A PROCESS FOR THE EXTRACTION OF THE TKANSURANIC ELEMENTS EROM NITRIC AC In WASTES UTILIZING MODIFIED PUREX SOLVENT*

3. Y. Zhu , R.Jiao , S.Wang , S.Fan , B.Liu , H.Zheng , S.Zhou and S.Chen , An extractant (TRPO) for the removal and recovery of actinides from high level radioactive liquid waste , ISEC'83 , Denver, Colorado USA , 1983

4. EXTRACTION OF NEPTUNIUM WITH DI-ISODECYL PHOSPHORIC ACID FROM NITRIC ACID SOLUTION CONTAINING HYDROGEN PEROXIDE

5. Ligands for f-element extraction used in the nuclear fuel cycle

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