[Cr(ttpy)2]3+ as a multi-electron reservoir for photoinduced charge accumulation-Reference-Cited by-同舟云学术

[Cr(ttpy)2]3+ as a multi-electron reservoir for photoinduced charge accumulation

Published:2019 Issue:20 Volume:48 Page:6800-6811
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Farran Rajaa¹²³⁴⁵,Le-Quang Long¹²³⁴⁵,Mouesca Jean-Marie¹⁶²⁷⁸,Maurel Vincent¹⁶²⁷⁸,Jouvenot Damien¹²³⁴⁵,Loiseau Frédérique¹²³⁴⁵,Deronzier Alain¹²³⁴⁵,Chauvin Jérôme¹²³⁴⁵^ORCID

Affiliation:

1. Univ. Grenoble Alpes

2. CNRS

3. DCM

4. F-38000 Grenoble

5. France

6. CEA

7. INAC

8. SyMMES

Abstract

Under visible light irradiation [Cr(ttpy)2]3+ can be reduced twice by a tertiary amine; the photoreduction processes are accelerated in the presence of [Ru(bpy)₃]²⁺ acting as an antenna thanks to an efficient electron transfer reaction from [Ru(bpy)₃]^2+* to [Cr(ttpy)₂]³⁺.

Funder

LABoratoires d’EXcellence ARCANE

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT00848A

Reference67 articles.

1. Photoinitiated Electron Collection in a Mixed-Metal Trimetallic Complex of the Form {[(bpy)2Ru(dpb)]2IrCl2}(PF6)5 (bpy = 2,2'-Bipyridine and dpb = 2,3-Bis(2-pyridyl)benzoquinoxaline)

2. Photoinduced Charge Accumulation in Molecular Systems

3. Ruthenium Photocatalysts Capable of Reversibly Storing up to Four Electrons in a Single Acceptor Ligand: A Step Closer to Artificial Photosynthesis