Probing the primary processes of a triazido–cobalt(iii) complex with femtosecond vibrational and electronic spectroscopies. Photochemical selectivity and multi-state reactivity
Author:
Affiliation:
1. Lehrstuhl für Molekulare Physikalische Chemie
2. Institut für Physikalische und Theoretische Chemie
3. Rheinische Friedrich-Wilhelms Universität
4. 53115 Bonn
5. Germany
Abstract
Femtosecond UV/Vis-to-MIR spectroscopies disclose the stereoselective events of ligand loss and solvent binding after LMCT-excitation of a Co-complex with multiple photolabile azido ligands.
Funder
Deutsche Forschungsgemeinschaft
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP04865H
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