Contrasting reactivity of B–Cl and B–H bonds at [Ni(IMes)<sub>2</sub>] to form unsupported Ni-boryls-Reference-Cited by-同舟云学术

Contrasting reactivity of B–Cl and B–H bonds at [Ni(IMes)₂] to form unsupported Ni-boryls

Published:2024 Issue:7 Volume:60 Page:874-877
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Audsley Gabrielle¹^ORCID,Carpentier Ambre²^ORCID,Pécharman Anne-Frédérique³,Wright James¹^ORCID,Roseveare Thomas M.⁴^ORCID,Clark Ewan R.⁵^ORCID,Macgregor Stuart A.²^ORCID,Riddlestone Ian M.¹^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, University of Surrey, Guildford GU2 7XH, UK

2. Institute of Chemical Sciences, Heriot-Watt University, Edinburgh, EH14 4AS, UK

3. Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, UK

4. Department of Chemistry, University of Sheffield, S3 7HF, UK

5. School of Physical Sciences, University of Kent, Canterbury, CT2 7NH, UK

Abstract

Whilst the oxidative addition of B–Cl bonds at [Ni(IMes)2] forms unsupported Ni-boryls the corresponding B–H bonds do not react via oxidative addition. Computational studies show that this is due to a fundamental change in mechanism.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D3CC05369E

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