Carbonyl and ester C–O bond hydrosilylation using κ4-diimine nickel catalysts

Author:

Rock Christopher L.1234,Groy Thomas L.1234,Trovitch Ryan J.1234ORCID

Affiliation:

1. School of Molecular Sciences

2. Arizona State University

3. Tempe

4. USA

Abstract

(Ph2PPrDI)Ni chemoselectively catalyzes α-allyl ester C–O bond hydrosilylation to prepare silyl esters with turnover frequencies of up to 990 h−1.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference137 articles.

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3. I. Ojima , Z.Li and J.Zhu , The Chemistry of Organic Silicon Compounds, Vol. 2 Part 2 , ed. Z. Rappoport and Y. Apeloig , John Wiley & Sons , Chichester , 1998 , pp. 1687–1792

4. The Addition of Silicon Hydrides to Olefinic Double Bonds. Part II. The Use of Group VIII Metal Catalysts

5. J. L. Speier , Advances in Organometallic Chemistry, Vol. 17 , ed. F. G. A. Stone and R. West , Academic Press , New York , 1979 , pp. 407–447

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