Rhodium<sup>III</sup>-catalyzed remote difunctionalization of arenes assisted by a relay directing group-Reference-Cited by-同舟云学术

Rhodium^III-catalyzed remote difunctionalization of arenes assisted by a relay directing group

Published:2022 Issue:24 Volume:13 Page:7347-7354
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Sun Lincong¹,Zhao Yuyao¹,Liu Bingxian¹^ORCID,Chang Junbiao¹,Li Xingwei¹²^ORCID

Affiliation:

1. NMPA Key Laboratory for Research and Evaluation of Innovative Drug, Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan 453007, China

2. Institute of Molecular Science and Engineering, Institute of Frontier and Interdisciplinary Sciences, Shandong University, Qingdao 250100, China

Abstract

Rhodium-catalyzed twofold C–H bond activation of para-olefin-tethered arenes has been realized using diverse unsaturated reagents. The overall reaction represents C–C or N–C difunctionalization of arenes with the generation of diverse 2,3-dihydrobenzofurans.

Funder

National Key Research and Development Program of China

National Natural Science Foundation of China

Central Plains Scholars and Scientists Studio Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC02205B

Reference144 articles.

1. Recent developments in natural product synthesis using metal-catalysed C–H bond functionalisation