The role of isovalency in the reactions of the cyano (CN), boron monoxide (BO), silicon nitride (SiN), and ethynyl (C2H) radicals with unsaturated hydrocarbons acetylene (C2H2) and ethylene (C2H4)
Author:
Affiliation:
1. Department of Chemistry
2. University of Hawai'i at Manoa
3. Honolulu, USA
4. Department of Chemistry and Biochemistry
5. Florida International University
6. Miami, USA
Abstract
The classification of chemical reactions based on shared characteristics is at the heart of the chemical sciences, and is well exemplified by Langmuir's concept of isovalency, in which ‘two molecular entities with the same number of valence electrons have similar chemistries’.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/CS/C3CS60328H
Reference56 articles.
1. THE ARRANGEMENT OF ELECTRONS IN ATOMS AND MOLECULES.
2. The inner wind of IRC+10216 revisited: new exotic chemistry and diagnostic for dust condensation in carbon stars
3. D. McElroy , C.Walsh , A. J.Markwick , M. A.Cordiner , K.Smith and T. J.Millar , arXiv.org , e-Print Arch ., Astrophys ., 2012, 1–18, arXiv:1212 6362v1211 [astro-ph SR]
4. Elementary Reactions and Their Role in Gas-Phase Prebiotic Chemistry
Cited by 27 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
1. Low-Temperature Gas-Phase Formation of Methanimine (CH2NH; X1A′)─the Simplest Imine─under Single-Collision Conditions;The Journal of Physical Chemistry Letters;2023-09-18
2. Gas-Phase Study of the Elementary Reaction of the D1-Ethynyl Radical (C2D; X2Σ+) with Propylene (C3H6; X1A′) under Single-Collision Conditions;The Journal of Physical Chemistry A;2022-03-15
3. A chemical dynamics study of the reaction of the methylidyne radical (CH, X2Π) with dimethylacetylene (CH3CCCH3, X1A1g);Physical Chemistry Chemical Physics;2022
4. A Crossed Molecular Beams and Computational Study of the Formation of the Astronomically Elusive Thiosilaformyl Radical (HSiS, X2A′);The Journal of Physical Chemistry Letters;2021-06-23
5. Thermochemical Trends in Carbon Chain Molecules HC2kH/HC2k-1H (k = 1–6) Studied by Explicitly Correlated CCSD(T)-F12b Composite Methods;The Journal of Physical Chemistry A;2021-06-14
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3