Rhodium(i)-catalyzed vinylation/[2 + 1] carbocyclization of 1,6-enynes with α-diazocarbonyl compounds
Author:
Affiliation:
1. Key Laboratory of Functional Molecular Engineering of Guangdong Province
2. Guangdong Engineering Research Center for Green Fine Chemicals
3. School of Chemistry and Chemical Engineering
4. South China University of Technology
5. Guangzhou 510641
Abstract
Rh(i)-catalyzed coupling–cyclization of enynes with diazo compounds has been developed to obtain versatile vinyl-substituted azabicyclo[3.1.0]hexanes.
Funder
National Basic Research Program of China
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/OB/C9OB01028A
Reference55 articles.
1. 1,2- and 2,1-Benzothiazines and Related Compounds
2. Copper-Catalyzed Oxidative Cross-Coupling of Sulfoximines and Alkynes
3. Radical cascade cyclization of 1,n-enynes and diynes for the synthesis of carbocycles and heterocycles
4. (Hetero)aromatics from dienynes, enediynes and enyne–allenes
5. Construction of [4.3.1]Propellanes via Molybdenum Fischer Carbene Complexes
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1. Recent Catalytic Routes to 3-Azabicyclo[3.1.0]hexane Derivatives;Russian Journal of Organic Chemistry;2024-03
2. Recent Advances in Cyclization Reactions of 1,6‐Enynes;Advanced Synthesis & Catalysis;2024-02-02
3. Expedient Synthesis of 6‐Functionalized Azabicyclo[4.1.0]heptane Derivatives;ChemistrySelect;2023-12-21
4. Cycloisomerization of enynones by aluminum halides: construction of bicyclo[3.1.0]hexanes by introducing halides;Organic Chemistry Frontiers;2023
5. Controlling Enantioselectivity and Diastereoselectivity in Radical Cascade Cyclization for Construction of Bicyclic Structures;Journal of the American Chemical Society;2021-07-14
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