Probing the speciation of quaternary ammonium polybromides by voltammetric tribromide titration
Author:
Affiliation:
1. Department of Chemistry
2. Sungshin W. University
3. Seoul 01133
4. South Korea
5. Department of Chemistry and Research Institute for Convergence of Basic Sciences
6. Hanyang University
7. Seoul 04763
Abstract
The speciation of quaternary ammonium polybromides (QBr2n+1) was quantitatively determined by voltammetric tribromide titration on a Pt ultramicroelectrode (UME).
Funder
National Research Foundation of Korea
Ministry of Education
Sungshin Women's University
Hanyang University
Publisher
Royal Society of Chemistry (RSC)
Subject
Electrochemistry,Spectroscopy,Environmental Chemistry,Biochemistry,Analytical Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/AN/C8AN00560E
Reference34 articles.
1. Recent Discoveries of Polyhalogen Anions - from Bromine to Fluorine
2. [C4MPyr]2[Br20]: Ionic-Liquid-Based Synthesis of a Three-Dimensional Polybromide Network
3. [(Ph)3PBr][Br7], [(Bz)(Ph)3P]2[Br8], [(n-Bu)3MeN]2[Br20], [C4MPyr]2[Br20], and [(Ph)3PCl]2[Cl2I14]: Extending the Horizon of Polyhalides via Synthesis in Ionic Liquids
4. Bromine-rich Zinc Bromides: Zn6Br12(18-crown-6)2×(Br2)5, Zn4Br8(18-crown-6)2×(Br2)3, and Zn6Br12(18-crown-6)2×(Br2)2
5. Structural Proof for a Higher Polybromide Monoanion: Investigation of [N(C3H7)4][Br9]
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