Base-catalyzed diastereodivergent thia-Michael addition to chiral β-trifluoromethyl-α,β-unsaturated <i>N</i>-acylated oxazolidin-2-ones-Reference-Cited by-同舟云学术

Base-catalyzed diastereodivergent thia-Michael addition to chiral β-trifluoromethyl-α,β-unsaturated N-acylated oxazolidin-2-ones

Published:2023 Issue:35 Volume:21 Page:7180-7187
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Racochote Sasirome¹,Naweephattana Phiphob¹,Surawatanawong Panida¹^ORCID,Kuhakarn Chutima¹^ORCID,Leowanawat Pawaret¹^ORCID,Reutrakul Vichai¹,Soorukram Darunee¹^ORCID

Affiliation:

1. Department of Chemistry and Center of Excellence for Innovation in Chemistry (PERCH-CIC), Faculty of Science, Mahidol University, Rama VI Road, Bangkok 10400, Thailand

Abstract

Base-catalyzed diastereodivergent thia-Michael addition to chiral β-trifluoromethyl-α,β-unsaturated N-acylated oxazolidin-2-ones leading to a series of chiral thia-Michael adducts in good yields with high diastereoselectivities is described.

Funder

Mahidol University

National Research Council of Thailand

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/OB/D3OB00999H

Reference67 articles.

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4. Recent Advances in Synthesis of Chiral Thioethers

5. Direct synthesis of 2-/3-(trifluoromethyl)thiochroman-4-ones: Superacid-induced tandem alkylation-cyclic acylation of benzenethiols using 2-/3-(trifluoromethyl)acrylic acid

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