Iron porphyrin catalysed light driven C–H bond amination and alkene aziridination with organic azides
Author:
Affiliation:
1. State Key Laboratory of Synthetic Chemistry
2. Department of Chemistry
3. The University of Hong Kong
4. China
5. Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis
6. HKU Shenzhen Institute of Research & Innovation
Abstract
An iron(iii) porphyrin catalysed sp3 C–H amination and alkene aziridination with broad substrate scope under mild conditions is conducted, with selectivity through the use of organic azides as the nitrogen source under blue LED light irradiation.
Funder
National Natural Science Foundation of China
Research Grants Council, University Grants Committee
Innovation and Technology Commission
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC00784F
Reference42 articles.
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3. Asymmetric Nitrene Transfer Reactions: Sulfimidation, Aziridination and C-H Amination Using Azide Compounds as Nitrene Precursors
4. Metal-Catalyzed Nitrogen-Atom Transfer Methods for the Oxidation of Aliphatic C–H Bonds
5. Recent advances in transition metal-catalyzed N-atom transfer reactions of azides
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