Iron porphyrin catalysed light driven C–H bond amination and alkene aziridination with organic azides

Author:

Du Yi-Dan12345ORCID,Zhou Cong-Ying1234ORCID,To Wai-Pong1234ORCID,Wang Hai-Xu1234ORCID,Che Chi-Ming12346ORCID

Affiliation:

1. State Key Laboratory of Synthetic Chemistry

2. Department of Chemistry

3. The University of Hong Kong

4. China

5. Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis

6. HKU Shenzhen Institute of Research & Innovation

Abstract

An iron(iii) porphyrin catalysed sp3 C–H amination and alkene aziridination with broad substrate scope under mild conditions is conducted, with selectivity through the use of organic azides as the nitrogen source under blue LED light irradiation.

Funder

National Natural Science Foundation of China

Research Grants Council, University Grants Committee

Innovation and Technology Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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