In situ observation of the magnetocaloric effect through neutron diffraction in the Tb(DCO2)3 and TbODCO3 frameworks

Author:

Dixey Richard J. C.12345,Manuel Pascal6785,Orlandi Fabio6785ORCID,Mukherjee Paromita910115,Dutton Siân E.910115ORCID,Stenning Gavin B. G.6785,Saines Paul J.12345ORCID

Affiliation:

1. School of Physical Sciences

2. Ingram Building

3. University of Kent

4. Canterbury

5. UK

6. ISIS Facility

7. STFC Rutherford Appleton Laboratory

8. Didcot

9. Cavendish Laboratory

10. University of Cambridge

11. Cambridge

Abstract

Understanding large entropy changes in efficient magnetocaloric materials is essential to design next-generation magnetocaloric devices. We report the large entropy change mechanism in two efficient magnetocaloric materials – TbODCO3 and Tb(DCO2)3.

Funder

Leverhulme Trust

University of Kent

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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