(7,8-Dicarba-<i>nido</i>-undecaboran-7-yl)acetic acid: synthesis of individual enantiomers and the first example of the determination of the absolute configuration of chiral monosubstituted <i>nido</i>-carborane-Reference-Cited by-同舟云学术

(7,8-Dicarba-nido-undecaboran-7-yl)acetic acid: synthesis of individual enantiomers and the first example of the determination of the absolute configuration of chiral monosubstituted nido-carborane

Published:2022 Issue:36 Volume:46 Page:17338-17347
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Gruzdev Dmitry A.¹^ORCID,Telegina Angelina A.¹^ORCID,Chulakov Evgeny N.¹,Levit Galina L.¹^ORCID,Krasnov Victor P.¹^ORCID

Affiliation:

1. Postovsky Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences, Ekaterinburg, 620108, Russia

Abstract

Starting from achiral closo-carborane and using natural amino acid as chiral auxiliary, individual (RP)- and (SP)-enantiomers of C-monosubstituted nido-carboranes were obtained.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NJ/D2NJ02994D

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