The structural evolution, optical gap, and thermoelectric properties of the RbPb<sub>2</sub>Br<sub>5</sub> layered halide, prepared by mechanochemistry-Reference-Cited by-同舟云学术

The structural evolution, optical gap, and thermoelectric properties of the RbPb₂Br₅ layered halide, prepared by mechanochemistry

Published:2022 Issue:17 Volume:10 Page:6857-6865
ISSN:2050-7526
Container-title:Journal of Materials Chemistry C
language:en
Short-container-title:J. Mater. Chem. C

Author:

Abia Carmen¹²,López Carlos A.¹³^ORCID,Gainza Javier¹^ORCID,Rodrigues João Elias F. S.¹⁴^ORCID,Ferrer Mateus M.⁵,Nemes N. M.¹⁶^ORCID,Dura Oscar J.⁷^ORCID,Martínez José L.¹^ORCID,Fernández-Díaz María T.²,Álvarez-Galván Consuelo⁸^ORCID,Németh Gergely⁹,Kamarás Katalin⁹,Fauth François¹⁰^ORCID,Alonso José A.¹^ORCID

Affiliation:

1. Instituto de Ciencia de Materiales de Madrid, CSIC, Cantoblanco, 28049 Madrid, Spain

2. Institut Laue Langevin, BP 156X, F-38042 Grenoble, France

3. Instituto de Investigación en Tecnología Química (UNSL-CONICET) and Facultad de Química, Bioquímica y Farmacia, Almirante Brown 1455, (5700) San Luis, Argentina

4. European Synchrotron Radiation Facility (ESRF), 71 Avenue des Martyrs, 38000 Grenoble, France

5. CCAF, PPGCEM/CDTec, Federal University of Pelotas, 96010-610 Pelotas, Rio Grande do Sul, Brazil

6. Departamento de Física de Materiales, Universidad Complutense de Madrid, E-28040 Madrid, Spain

7. Departamento de Física Aplicada, Universidad de Castilla-La Mancha, Ciudad Real, E-13071, Spain

8. Instituto de Catálisis y Petroleoquímica, CSIC, Cantoblanco, 28049 Madrid, Spain

9. Institute for Solid State Physics and Optics, Wigner Research Centre for Physics, P. O. Box 49, Budapest, H-1525, Hungary

10. CELLS–ALBA synchrotron Light Facility, Cerdanyola del Valles, Barcelona, E-08290, Spain

Abstract

RbPb2Br5 was studied by SXRD and NPD data from 15 to 573 K, yielding information on Rb–Br and Pb–Br chemical bonds. The electron lone pair of Pb2+ is visualized. Photoluminescence excitation and emission spectra suggest applications in photovoltaics.

Funder

Ministerio de Economía y Competitividad

Ministerio de Ciencia e Innovación

Nemzeti Kutatási Fejlesztési és Innovációs Hivatal

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/TC/D2TC00653G

Reference50 articles.

1. Iodide management in formamidinium-lead-halide–based perovskite layers for efficient solar cells