Total scattering reveals the hidden stacking disorder in a 2D covalent organic framework

Author:

Pütz Alexander M.12345ORCID,Terban Maxwell W.123ORCID,Bette Sebastian123ORCID,Haase Frederik123ORCID,Dinnebier Robert E.123ORCID,Lotsch Bettina V.12345ORCID

Affiliation:

1. Max Planck Institute for Solid State Research

2. 70569 Stuttgart

3. Germany

4. Department of Chemistry

5. University of Munich (LMU)

Abstract

With total scattering methods and stacking fault simulations, we observe previously predicted random local layer offsets in a COF, which are typically disguised by the apparent crystallographic symmetry but strongly influence properties.

Funder

Deutsche Forschungsgemeinschaft

H2020 European Research Council

BASF

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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