Total scattering reveals the hidden stacking disorder in a 2D covalent organic framework
Author:
Affiliation:
1. Max Planck Institute for Solid State Research
2. 70569 Stuttgart
3. Germany
4. Department of Chemistry
5. University of Munich (LMU)
Abstract
With total scattering methods and stacking fault simulations, we observe previously predicted random local layer offsets in a COF, which are typically disguised by the apparent crystallographic symmetry but strongly influence properties.
Funder
Deutsche Forschungsgemeinschaft
H2020 European Research Council
BASF
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC03048A
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